基于热力学计算的矿井支架用FeNiCrBC系激光熔覆层成分优化

Optimization of compositions of Fe Ni Cr BC laser cladding layer for mine support based on Thermo-Calc

  • 摘要: 针对矿井支架用FeNiCrBC熔覆层耐腐蚀性差和易开裂的问题,通过调整熔覆层内Ni,Nb元素的含量增加熔覆层内残余奥氏体的含量并降低晶间贫铬现象,从而达到降低裂纹敏感性并提升抗腐蚀性的目的。文中利用Thermo-Calc热力学软件研究了Ni,Nb元素含量的变化对矿井支架用FeNiCrBC熔覆层中显微组织和析出相的影响,并在此基础上对FeNiCrBC合金成分进行了优化调整。结果表明,在FeNiCrBC系熔覆层中,Ni含量由1%增加到8%的过程中,σ相的比例随着Ni含量的增加而降低;Ni含量为4%时,残余奥氏体比例达到最大;Nb含量由0.3%增加到2.0%的过程中,Cr元素在马氏体中的含量先增大后趋于平稳,而在碳化物及硼化物中的含量逐渐降低,Nb元素在碳化物及硼化物中的含量逐渐增大。当FeNiCrBC熔覆层中Ni含量和Nb含量分别为4%和1%时,熔覆层抗腐蚀性明显上升,裂纹敏感性显著降低。

     

    Abstract: Aiming at the problem of poor corrosion resistance and easy cracking of the Fe Ni Cr BC cladding layer for mine supports,the content of Ni and Nb elements in the cladding layer was adjusted to increase the content of retained austenite in the cladding layer and reduce the phenomenon of intergranular chromium depletion,so as to arrive the purpose of decreasing crack sensitivity and improving corrosion resistance. In this study,the influence of contents of Ni and Nb elements on the microstructure and precipitated phase in Fe Ni Cr BC cladding layer was investigated through the thermodynamics software Thermo-Calc. The chemical compositions of cladding layer were optimized based on the research results. The result showed that the percentage of σ phase decreased with the Ni content increasing from 1% to 8%. The proportion of retained austenite in Fe Ni Cr BC cladding layer reached the maximum when the Ni content was 4%. With the addition amount of Ni element increasing from 0.3% to 2.0%,the Cr content in martensite first increased and then tended to be steady,and it in carbide and boride decreased gradually,while the amount of Nb in such two compounds increased. After the elements Ni and Nb were adjusted to 4% and 1% respectively,the corrosion resistance of Fe Ni Cr BC cladding layer got improved apparently,and also the cracking susceptibility decreased obviously.

     

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