Fe-Cr-B-C系耐磨堆焊合金组织与性能

Microstructure and properties of Fe-Cr-B-C series wear-resistant surfacing alloys

  • 摘要: 为了探讨合金元素Cr,C对高硼铁基堆焊合金组织结构的影响,采用气体保护焊堆焊技术,通过调整金属粉芯焊丝中高碳铬铁的添加量,在Q235钢板表面制备不同高碳铬铁含量的Fe-Cr-B-C堆焊合金,采用金相显微镜、扫描电镜、能谱(energy dispersive spectrometer,EDS)及X射线衍射(X-ray diffraction,XRD)等分析测试方法,分析不同合金元素Cr,C含量对堆焊合金组织和性能的影响。结果表明,堆焊合金的组织为马氏体 + 网状(Fe, Cr)3(B, C)及少量的微量M7C3;随着高碳铬铁粉添加量的增加,网状(Fe, Cr)3(B, C)体积分数增加,堆焊合金中的马氏体具有较高的硬度,合金元素Cr能够使基体组织固溶强化,网状碳化物(Fe, Cr)3(B, C)作为耐磨骨架,阻碍磨料在磨损过程中的挤压与切削作用,使堆焊层耐磨性均高于65Mn钢3~4倍,其磨损机理为微犁沟。

     

    Abstract: In order to investigate the effect of alloying elements Cr and C on the microstructure of high boron iron-based surfacing alloys, gas shielded surfacing technology was used to prepare different types of high-carbon ferrochromium on the surface of Q235 steel plate by adjusting the addition amount of high-carbon ferrochromium in the metal powder cored wire. The Fe-Cr-B-C surfacing alloy with high carbon and ferrochromium content was analyzed by metallographic microscope, scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD), and other analysis and testing methods to analyze the effects of different alloying elements Cr and C content on the microstructure and properties of the surfacing alloy. The results show that the microstructure of the surfacing alloy is martensite + network (Fe, Cr)3(B, C), and a small amount of M7C3. The volume fraction of (Fe, Cr)3(B, C) increases, the martensite in the surfacing alloy has higher hardness, the alloy element Cr can make the matrix structure solid solution strengthening, and the network carbide (Fe, Cr)3(B, C) As a wear-resistant skeleton, it hinders the extrusion and cutting of abrasives in the process of wear, so that the wear resistance of the surfacing layer is 3-4 times higher than that of 65Mn steel, and the wear mechanism is micro-furrowing.

     

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