回流时间对纯铜基板Sn0.3Ag0.7Cu钎料钎焊焊点组织和力学性能影响

Effect of reflow time on microstructure and mechanical properties of soldered joints of pure copper substrate with Sn0.3Ag0.7Cu solder

  • 摘要: 以Sn0.3Ag0.7Cu为钎料,纯Cu板为基板,采用过渡液相扩散焊工艺制备Cu/Cu3Sn/Cu6Sn5/Cu3Sn/Cu多层结构全金属间化合物焊点,通过扫描电子显微镜和能谱仪分析了焊点的组织形貌和成分,测试了焊点的抗剪强度,研究了界面金属间化合物的生长机理。结果表明,由于温度梯度的影响,冷端Cu6Sn5生长速度大于热端。回流时间为5 h时,焊缝形成全金属间化合物,焊缝界面较为平整且无缺陷,抗剪强度由32.16 MPa降至21.29 MPa,降低了33.8%,断裂模式由塑性断裂最终演变为脆性断裂。

     

    Abstract: Taking Sn0.3Ag0.7Cu as solder and pure Cu plate as substrate, Cu/Cu3Sn/Cu6Sn5/Cu3Sn/Cu multilayer structure all-intermetallic compound soldered joints were prepared by transient liquid phase diffusion welding process. Scanning electron microscope and energy dispersive spectrometer were used to analyze microstructure and composition of soldered joints, shear strength of soldered joints was tested, and growth mechanism of intermetallic compounds at interface was studied. The results showed that growth rate of Cu6Sn5 at the cold end was greater than that at the hot end due to the influence of temperature gradient. When reflow time was 5 h, all-intermetallic compound was formed in weld, interface of weld was relatively flat and free of defect, shear strength was reduced from 32.16 MPa to 21.29 MPa with a decrease of 33.8%, and fracture mode evolved from plastic fracture to brittle fracture.

     

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