硫化氢环境中X80管线钢焊接粗晶热影响区的断裂韧性

Fracture toughness of CGHAZ of X80 pipeline steel in hydrogen sulfide environment

  • 摘要:
    目的 为了评估空气和硫化氢环境下X80管线钢粗晶热影响区(CGHAZ)的断裂韧性差异,分析了环境因素对断裂韧性的影响。
    方法 利用三点弯试验测试了CGHAZ的断裂韧性,并利用SEM对CTOD试样断口微观形貌和裂纹扩展路径进行了分析,并探究了H2S环境对CGHAZ断裂韧性的影响机制。
    结果 结果表明,CGHAZ在H2S介质中的断裂韧性发生了明显降低,其CTOD平均值由0.335 mm降低至0.093 mm,降低了约72%。CGHAZ在空气环境中的断口形貌主要为韧窝特征,而H2S环境中的断口主要是韧窝和准解理面共存的混合断裂特征。Ti-Mn-Fe的氧化物是准解理面的起裂源。
    结论 氢致弱键(HEDE)和氢增强局部塑性(HELP)是造成CGHAZ在H2S环境下断裂韧性降低的主要机制。

     

    Abstract: Objective This study aims to evaluate the fracture toughness of coarse grain heat-affected zone (CGHAZ) of X80 pipeline steel in air and H2S environment. It analyzes the effect of environment on the fracture toughness. Methods Three-point bending test is conducted to study the fracture toughness. The fracture morphology and crack propagation path of CTOD specimen are analyzed by SEM, and the influence mechanism of H2S environment on fracture toughness of CGHAZ is explained. Results The results show that the fracture toughness of CGHAZ in H2S is significantly reduced, and the average CTOD value is reduced by 72%, from 0.335 mm to 0.093 mm. The fracture morphology in the air is mainly dimple, while the fracture in the H2S is mainly a mixed fracture feature of dimple and quasi-cleavage plane. The oxide of Ti-Mn-Fe is the initiation site of quasi cleavage plane. Conclusion Hydrogen-enhanced decohesion (HEDE) and hydrogen enhanced local plasticity (HELP) are the main mechanisms for the reduction of fracture toughness of CGHAZ in the H2S environment.

     

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