烧结温度对FeCu基烧结胎体组织及性能的影响

Effect of sintering temperature on microstructure and properties of FeCu-based matrix

  • 摘要: 为降低Fe基粉末的烧结温度,在Fe基粉末中添加一定比例的CuZnSnMnSi粘结剂粉末,研究了不同烧结温度下烧结胎体的组织及性能。结果表明,烧结胎体主要由Cu基固溶体、Fe基固溶体及(Mn,Si)x·Oy相组成,随着烧结温度的升高,烧结胎体的相对密度先增大后减小,条带状(Mn,Si)x·Oy相逐渐聚集长大成圆球状;随着烧结温度的升高,烧结胎体的抗弯强度先升高后降低,在烧结温度为750 ℃时,烧结胎体具有最大的平均抗弯强度684 MPa;烧结胎体的抗弯强度主要取决于相对密度和(Mn,Si)x·Oy相,界面孔隙、条带状或大尺寸圆球状(Mn,Si)x·Oy相的存在是抗弯强度降低的主要原因。

     

    Abstract: To reduce the sintering temperature of Fe-based powder, CuZnSnMnSi powder binder was added in Fe-based powder, and the microstructure and properties of sintered matrix at different sintering temperatures were studied. Experimental results and analysis show that the sintered matrix is mainly composed of Cu-based solid solution, Fe-based solid solution and (Mn,Si)x·Oy composite phase. With the increasing of sintering temperature, the relative density of sintered matrix first increases and then decreases, the banded (Mn,Si)x·Oy composite phase gradually gather and grow into spherical shapes. With the increasing of sintering temperature, bending strength of sintered matrix decreases after rising first, and the maximum average bending strength is 683.6 MPa at the sintering temperature of 750 ℃. Bending strength of sintered matrix depends mainly on the relative density and banded (Mn,Si)x·Oy composite phase. The presence of interfacial pores and banded or large-sized spherulitic (Mn,Si)x·Oy composite phase is the main reason for decrease of bending strength.

     

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