Zn-Al系钎料成分对钢/铝管磁脉冲半固态钎焊组织及性能的影响

Effect of composition of Zn-Al series solder on microstructure and properties of steel/aluminum pipes by magnetic pulse semi-solid soldering

  • 摘要:
    目的 旨在探究不同组分Zn-Al钎料与不同组分Zn-Al-xSi钎料在进行钢/铝管磁脉冲半固态钎焊时Al和Si含量对元素扩散过程、界面组织的影响及变化规律。
    方法 通过剪切试验、显微硬度、电子探针及能谱分析等方法,探究Zn-Al钎料、Zn-Al-xSi钎料焊接接头的显微组织及力学性能,重点分析金属间化合物对焊接接头性能的影响。
    结果 Zn15Al钎料较Zn3Al,Zn22Al更适合钢、铝钎焊,接头力学性能较好;Zn-Al钎料中加入Si元素可以通过形成性能较好Si,Al和Fe三元金属间化合物抑制脆性Fe/Al金属间化合物的形成和生长,并提升接头力学性能。
    结论 在Zn-Al钎料中,Zn15Al接头抗剪强度最高,达到38.49 MPa。在Zn-Al-xSi钎料中,随Si含量(质量分数)增加,钎缝晶粒细化;Si含量为1.5%时,达到最大45.07 MPa。

     

    Abstract: Objective This study aims to investigate effects of Al and Si content on elemental diffusion process and interfacial microstructure during magnetic pulse semi-solid soldering of steel/aluminum pipes with Zn-Al and Zn-Al-xSi solder, as well as their variation patterns. Methods Microstructure and mechanical properties of soldered joints with Zn-Al and Zn-Al-xSi solder were examined through shear tests, microhardness measurements, electron probe microanalysis (EPMA) and energy dispersive spectroscopy (EDS). Special emphasis was placed on analyzing the influence of intermetallic compounds on performance of soldered joints. Results The Zn15Al solder demonstrated superior suitability for steel/aluminum soldering compared to Zn3Al and Zn22Al, yielding better mechanical properties of soldered joints. The addition of Si to Zn-Al solder promoted the formation of ternary Si-Al-Fe intermetallic compounds with favorable properties, which effectively suppressed the formation and growth of brittle Fe/Al intermetallic compounds and enhanced mechanical properties of soldered joints. Conclusion Among Zn-Al solder, Zn15Al joint achieves the highest shear strength of 38.49 MPa. For Zn-Al-xSi solder, increasing Si content leads to grain refinement in the soldering seam. The optimal performance with shear strength of 45.07 MPa occurs at 1.5 wt.% Si.

     

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