不锈钢焊接回火色的耐点蚀性能与处理

Pitting corrosion resistance and treatment of heat tint in stainless steel welding

  • 摘要:
    目的 旨在明确不锈钢焊接回火色对其耐蚀性能的影响,特别是点蚀行为,为工程中焊后处理提供依据。
    方法 制备了不同颜色的焊接回火色,建立其与焊接峰值温度的关系;测量了点蚀电位,并与母材对比;采用多种焊后处理方法(如粗磨、细磨、酸洗等)评估其耐点蚀性能。
    结果 焊接回火色形成温度高于热处理回火色(最浅颜色在430 ℃以上);点蚀电位随颜色加深明显下降,浅黄色已无法满足流体容器要求;处理后耐点蚀性能与表面粗糙度正相关,粗糙度越大,性能越差。
    结论 焊接回火色显著降低耐蚀性,工程中可采用粗磨+细磨或电解替代酸洗;高Cr不锈钢回火色形成温度更高、更难酸洗。

     

    Abstract: Objective The aim was to clarify effect of heat tint in stainless steel welding on its pitting corrosion resistance, especially the pitting behavior, and to provide a basis for post-weld treatment in engineering. Methods Welding heat tint with different colors was prepared and correlated with welding peak temperatures. Pitting potential was measured and compared with that of base metals. Various post-weld treatment methods such as rough grinding, fine grinding and pickling were applied to evaluate pitting corrosion resistance. Results The formation temperature of welding heat tint was higher than that of heat treatment heat tint (lightest color above 430 ℃). Pitting potential decreased significantly with the darker colors, and light yellow could not meet the requirements for fluid containers. Corrosion resistance after treatment was positively correlated with surface roughness. The greater the roughness, the worse the performance. Conclusion Welding heat tint markedly reduces corrosion resistance. Rough grinding and fine grinding or electrolysis can replace pickling in engineering. High-Cr stainless steel requires higher temperature for heat tint formation and is more difficult to pickle.

     

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